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Chloro(1,5-cyclooctadiene)iridium(I) dimer

Catalog Number ACM12112673-4
CAS 12112-67-3
Structure {[CurrentData.Name]}
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride;
Synonyms Bis(1,5-cyclooctadiene)diiridium(I) dichloride
Molecular Weight 671.71
Molecular Formula C16H24Cl2Ir2
Canonical SMILES C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Ir].[Ir]
InChI InChI=1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H,3-6H2;2*1H;/p-2/b2*2-1-,8-7-;
InChI Key SHZHQWGWORCBJK-MIXQCLKLSA-L
Melting Point 205 °C
Purity 99%
Appearance Red brown powder
Application 1. Precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins.

2. Precursor to catalyst for enantioselective reduction of imines.

3. Precursor to catalyst for allylic alkylation.

4. Precursor to catalyst for allylic amination and etherification.

5. Precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes.

6. Ir-catalyzed addition of acid chlorides to terminal alkynes.

7. Intramolecular hydroamination of unactivated alkenes with secondary alkyl- and arylamines.

8. Enantioselective [2+2] cycloaddition.

9. Silyl-directed, Ir-catalyzed ortho-borylation of arenes.

10. Ir-catalyzed cross-coupling of styrene derivatives with allylic carbonates.

11. Transfer hydrogenative C-C coupling
Storage 2-8°C
Complexity 72.6
Covalently-Bonded Unit Count 6
EC Number 235-170-7
Exact Mass 670.04902
Heavy Atom Count 20
Hydrogen Bond Acceptor Count 2
Monoisotopic Mass 672.05135
Rotatable Bond Count 0
Topological Polar Surface Area 0 Ų
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